{"id":536,"date":"2014-11-23T12:05:50","date_gmt":"2014-11-23T04:05:50","guid":{"rendered":"https:\/\/www.maituflow.com\/?p=536"},"modified":"2014-11-23T12:08:57","modified_gmt":"2014-11-23T04:08:57","slug":"progress-of-bentonite-in-wastewater-treatment","status":"publish","type":"post","link":"https:\/\/www.maituflow.com\/progress-of-bentonite-in-wastewater-treatment\/","title":{"rendered":"\u81a8\u6da6\u571f\u5728\u5e9f\u6c34\u5904\u7406\u4e2d\u7684\u7814\u7a76\u8fdb\u5c55"},"content":{"rendered":"

\u6458\u8981\uff1a\u968f\u7740\u5de5\u4e1a\u7684\u9ad8\u901f\u53d1\u5c55\u548c\u57ce\u5e02\u5316\u8fdb\u7a0b\u7684\u52a0\u5feb\uff0c\u6c34\u6c61\u67d3\u95ee\u9898\u65e5\u8d8b\u4e25\u91cd\uff0c\u5e9f\u6c34\u5904\u7406\u5df2\u6210\u4e3a\u4e00\u4e2a\u4e9f\u5f85\u89e3\u51b3\u7684\u95ee\u9898\u3002\u81a8\u6da6\u571f\u5177\u6709\u826f\u597d\u7684 \u79bb\u5b50\u4ea4\u6362\u6027\u548c\u5438\u9644\u6027\uff0c\u5176\u5728\u91cd\u91d1\u5c5e\u5e9f\u6c34\u3001\u5370\u67d3\u5e9f\u6c34\u548c\u6709\u673a\u5e9f\u6c34\u5904\u7406\u5e94\u7528\u7814\u7a76\u4e2d\u53d6\u5f97\u4e86\u8f83\u597d\u7684\u6548\u679c\uff0c\u968f\u7740\u65b0\u578b\u81a8\u6da6\u571f\u6750\u6599\u7684\u7814\u7a76\u5236\u5907\uff0c\u5b83\u5728\u5e9f\u6c34\u5904\u7406\u9886\u57df\u7684\u5e94\u7528\u4f1a\u8d8a\u6765\u8d8a\u5e7f\u6cdb\u3002<\/p>\n

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\u81a8\u6da6\u571f\u5728\u6c34\u5904\u7406\u4e2d\u7684\u5e94\u7528\u53ef\u8ffd\u6eaf\u523020\u4e16\u7eaa30\u5e74\u4ee3\u3002Smith \u7b49\u53d1\u73b0\u8499\u8131\u77f3\u80fd\u4ece\u6c34\u6eb6\u6db2\u4e2d\u5438\u6536\u80bc\u7b49\u6709\u673a\u9633\u79bb\u5b50\uff0cOlin \u7b49\u5c06\u81a8\u6da6\u571f\u7528\u4f5c\u6df7 \u51dd\u5242\u6765\u5904\u7406\u6c34\u548c\u5e9f\u6c34\u300220\u4e16\u7eaa 80\u5e74\u4ee3\u4ee5\u6765,\u81a8\u6da6\u571f\u5728\u73af\u5883\u4fdd\u62a4\u4e2d\u7684\u5e94\u7528\u53d6\u5f97\u4e86\u8f83\u5927\u8fdb\u5c55\uff0c\u5b83\u4e3b\u8981\u88ab\u7528\u4e8e\u5e9f\u6c34\u51c0\u5316\u5904\u7406\u3001\u6cb9\u6c61\u5904\u7406\u3001\u5e9f\u5851\u6599\u5904\u7406\u3001\u57ce\u5e02\u5783\u573e\u5904\u7406\u3001\u7a7a\u6c14\u51c0\u5316\u4e0e\u5e9f\u6c14\u5904\u7406\u3001\u653e\u5c04\u6027\u5e9f\u7269\u548c\u5371\u9669\u5e9f\u7269\u7684\u5904\u7406\u5904\u7f6e\uff1b\u5176\u4e2d\u7528\u4e8e\u5e9f \u6c34\u5904\u7406\u7684\u62a5\u9053\u6700\u591a\u3002<\/p>\n

1 \u5929\u7136\u81a8\u6da6\u571f\u5728\u5e9f\u6c34\u5904\u7406\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n

\u5929\u7136\u81a8\u6da6\u571f\u7531\u4e8e\u5177\u6709\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\u3001\u79bb\u5b50\u4ea4\u6362\u5bb9\u91cf\u53ca\u8f83\u597d\u7684\u5438\u9644\u6027\u80fd\u7b49\u7279\u70b9\uff0c\u53ef\u7528\u4e8e\u5e9f\u6c34\u4e2d\u91cd\u91d1\u5c5e\u7b49\u6c61\u67d3\u7269\u7684\u5438\u9644\u5904\u7406\u3002Anoop K, Vi-rarghavan T \u7b49(1998)[4\uff0c5]\u5c06\u81a8\u6da6\u571f\u5236\u6210\u5177\u6709\u591a\u5b54\u7684\u73e0\u72b6\u9897\u7c92\uff0c\u5728 pH \u503c\u4e3a4.5~6.9 \u65f6\u53bb\u9664\u6c34\u6eb6\u6db2\u4e2d\u7684 Cd2+ \u548c Cu2+\uff0c\u5176\u5438\u9644\u91cf\u5206\u522b\u4e3a 23.81mg\/g \u548c13.15mg\/g\u3002\u676d\u745a\u7b49[6]\u7814\u7a76\u4e86\u81a8\u6da6\u571f\u5438\u9644 – \u7d6e\u51dd\u6cd5\u5904\u7406\u6c61\u6c34\u4e2d\u7684\u91cd\u91d1\u5c5e\u79bb\u5b50\uff0c\u7ed3\u679c\u8868\u660e\uff0c\u5229\u7528\u5929\u7136\u81a8\u6da6\u571f\u5438\u9644\u91cd\u91d1\u5c5e\u79bb\u5b50\u53d6\u5f97\u4e86\u6210\u529f\uff1b\u5bf9\u9752\u5c9b\u84c4\u7535 \u6c60\u5382\u542b\u94c5\u6c61\u6c34\u8fdb\u884c\u4e86\u5c0f\u8bd5\uff0c\u94c5\u8131\u51fa\u7387\u4e3a 93.1\uff05\uff0c\u805a\u5408\u6c2f\u5316\u94dd\u662f\u8f83\u597d\u7684\u7d6e\u51dd \u5242\u3002Nassem\u7b49(1996)[7]\u5c06\u5929\u7136\u81a8\u6da6\u571f\u63d0\u7eaf\uff0c\u5728 150~200\u2103\u4e0b\u5e72\u71e5\uff0c\u7528\u4e8e\u5404\u79cd \u6eb6\u6db2\uff08\u6c34\u3001\u785d\u9178\u3001\u76d0\u9178\u3001\u9ad8\u6c2f\u9178\uff09\u4e2d Pb2+ \u7684\u53bb\u9664\uff0c\u5728\u6700\u4f73\u6761\u4ef6\u4e0b\uff0c\u81a8\u6da6\u571f\u5bf9\u56db \u79cd\u6eb6\u6db2 Pb2+ \u7684\u53bb\u9664\u7387\u5206\u522b\u4e3a 98\uff05\u300178\uff05\u300186\uff05\u300179\uff05\u3002\u6c88\u5b66\u4f18\u7b49(1998)[8]\u63a2 \u8ba8\u4e86\u5229\u7528\u81a8\u6da6\u571f\u3001\u9ad8\u5cad\u571f\u3001\u4f0a\u5229\u77f3\u7b49\u4e09\u79cd\u7c98\u571f\u53bb\u9664\u5e9f\u6c34\u4e2d Ni\u3001Cu\u3001Zn\u3001Cd \u7684\u9002\u5b9c\u6761\u4ef6\uff0c\u7ed3\u679c\u8868\u660e\uff0c\u81a8\u6da6\u571f\u5e94\u7528\u4e8e\u7535\u9540\u5e9f\u6c34\u4e2d\u91cd\u91d1\u5c5e\u79bb\u5b50\u7684\u5904\u7406\u6548\u679c \u597d\u4e8e\u5176\u4ed6\u4e24\u79cd\u7c98\u571f\uff0c\u4f46 pH \u503c\u7684\u5f71\u54cd\u6548\u679c\u8f83\u5927\u3002<\/p>\n

2 \u6539\u6027\u81a8\u6da6\u571f\u53bb\u9664\u5e9f\u6c34\u4e2d\u91cd\u91d1\u5c5e\u79bb\u5b50<\/strong><\/p>\n

2.1 \u53bb\u9664 Ni2+<\/strong><\/p>\n

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2.2 \u8131\u51fa Cu2+<\/strong><\/p>\n

O.Abollino\u7b49\u56fa\u5b9a\u94a0\u5316\u81a8\u6da6\u571f\u7684\u7528\u91cf\uff0c\u8fdb\u884c\u4e86\u5438\u9644\u6c34\u4e2d Cd\u3001Cr\u3001Cu\u3001Mn\u3001Ni\u3001Pb \u548c Zn \u7684\u7814\u7a76\uff0c\u53d1\u73b0 pH \u503c\u7684\u6ce2\u52a8\u4e25\u91cd\u5f71\u54cd\u4e86\u5bf9 Cu\u3001Pb \u548cCd \u7684\u5438\u6536\uff0c\u91d1\u5c5e\u4e0e\u81a8\u6da6\u571f\u7ec4\u6210\u7684\u7edc\u5408\u7269\u4f1a\u5f71\u54cd\u91d1\u5c5e\u7684\u5438\u9644\uff0c\u5176\u5f71\u54cd\u7a0b\u5ea6 \u4ece\u8f7b\u5230\u91cd\u4f9d\u6b21\u662f\uff1aMn\u3001Pb\u3001Cd\u3001Zn\u3001Ni\u3001Cu\u3001Cr\u3002\u6731\u5229\u4e2d\u7b49(1993)\u7814\u7a76\u4e86\u9178\u6027\u81a8 \u6da6\u571f\u4e0e\u539f\u571f\u5904\u7406\u5e9f\u6c34\u4e2d\u94c5\u3001\u94ec\u3001\u9549\u3001\u94dc\u3001\u950c\u3001\u954d\u7684\u9002\u5b9c\u6761\u4ef6\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c \u9178\u6027\u81a8\u6da6\u571f\u5bf9\u5e9f\u6c34\u4e2d\u91cd\u91d1\u5c5e\u79bb\u5b50\u7684\u53bb\u9664\u6548\u679c\u8f83\u597d\uff0c\u4e14\u6613\u5206\u79bb\u3002Mortarhes \u7b49(1995)\u63d0\u51fa\u805a\u5408\u7f9f\u57fa\u94dd\u81a8\u6da6\u571f\u4e0e\u805a\u5408\u73af\u6c27\u4e59\u70f7\u53cd\u5e94\u5f97\u5230\u7684\u65e0\u673a\uff0d\u6709\u673a \u81a8\u6da6\u571f\u590d\u5408\u6750\u6599\u80fd\u591f\u6709\u6548\u5730\u53bb\u9664\u6eb6\u6db2\u4e2d\u7684 Cu2+\u3001Hg2+\u3001Cd2+\u3001Ni2+ \u7b49\u91cd\u91d1\u5c5e \u79bb\u5b50\u3002<\/p>\n

3 \u6539\u6027\u81a8\u6da6\u571f\u5904\u7406\u5370\u67d3\u5e9f\u6c34<\/strong><\/p>\n

\u5927\u91cf\u7814\u7a76\u8868\u660e\uff0c\u81a8\u6da6\u571f\u5bf9\u5370\u67d3\u5e9f\u6c34\u7684\u5904\u7406\u6548\u679c\u751a\u4f73\uff0c\u662f\u9ad8\u6548\u5ec9\u4ef7\u7684 \u67d3\u6599\u5e9f\u6c34\u7684\u5438\u9644\u5242\u3002
\n\u590f\u65b0\u594e\u7b49\u5c06\u9499\u57fa\u81a8\u6da6\u571f\u9178\u6027\u6d3b\u5316\uff0c\u7136\u540e\u5bf9\u5370\u67d3\u5e9f\u6c34\u8131\u8272\u5904\u7406\uff0c\u5f53 pH \u503c\u4e3a 7.0~8.0\uff0c\u52a0\u5165\u91cf\u8fbe\u5230 30g\/L\u5728\u5ba4\u6e29\u6761\u4ef6\u4e0b\u6405\u62cc 35min \u65f6\uff0c\u5176\u4e00\u6b21\u6027 COD\u53bb\u9664\u7387\u8fbe 76\uff05\uff0c\u8272\u5ea6\u53bb\u9664\u7387\u8fbe 87\uff05\uff1b\u82e5\u7ecf\u53cc\u5c42\u6ee4\u6599\u67f1\u8fdb\u884c\u8fc7 \u6ee4\u5904\u7406\uff0c\u8272\u5ea6\u53bb\u9664\u7387\u8fbe 93\uff05\u4ee5\u4e0a\uff0cCOD\u53bb\u9664\u7387\u8fbe 78\uff05\uff0c\u5904\u7406\u540e\u7684\u5370\u67d3\u5e9f \u6c34\u8fbe\u5230\u56fd\u5bb6\u6392\u653e\u6807\u51c6\u3002\u65e0\u673a\u7269\u6216\u65e0\u673a\u5927\u5206\u5b50\u96c6\u5408\u4f53\u6539\u6027\u81a8\u6da6\u571f\u5bf9\u7ea2\u8272\u67d3 \u6599\u7684\u8131\u8272\u6027\u80fd\u53ca\u8131\u8272\u673a\u7406\u5df2\u7ecf\u88ab\u7814\u7a76\uff0c\u7ed3\u679c\u8868\u660e\uff0c\u6539\u6027\u81a8\u6da6\u571f\u7684\u8131\u8272\u80fd\u529b \u6bd4\u539f\u571f\u6709\u8f83\u5927\u7684\u589e\u5f3a\u3002\u5f20\u5efa\u82f1\u7b49\u7528\u9178\u6027\u81a8\u6da6\u571f\u6dfb\u52a0 PAC\u7b49\u5236\u5f97\u6539\u6027\u81a8\u6da6 \u571f\uff0c\u7528\u4e8e\u5370\u67d3\u5e9f\u6c34\u5904\u7406\uff0cCOD\u53bb\u9664\u7387\u8fbe 60%\u4ee5\u4e0a\u3002\u90b5\u9896\u7b49\u5728\u81a8\u6da6\u571f\u4e2d\u5f15\u5165 \u65e0\u673a\u6539\u6027\u5242\uff0c\u6539\u6027\u540e\u7684\u81a8\u6da6\u571f\u5438\u9644\u5904\u7406\u5e9f\u6c34\u4e2d\u5206\u6563\u5927\u7ea2\u65f6\uff0c\u5e73\u8861\u901f\u5ea6\u5feb\uff0c \u5438\u9644\u6027\u80fd\u4f73\u3002<\/p>\n

4 \u6539\u6027\u81a8\u6da6\u571f\u5904\u7406\u6709\u673a\u6c61\u67d3\u7269<\/strong><\/p>\n

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\n\u6731\u5229\u4e2d\u7b49\u5bf9\u6eb4\u5316\u5341\u516d\u70f7\u57fa\u4e09\u7532\u94f5\uff08CTMAB\uff09\u6539\u6027\u7c98\u571f\u7684\u5236\u5907\u53ca \u5438\u9644\u5904\u7406\u6c34\u4e2d\u6709\u673a\u7269 – \u82ef\u915a\u3001\u82ef\u80fa\u548c\u785d\u57fa\u82ef\u915a\u8fdb\u884c\u4e86\u7814\u7a76\uff0c\u5b9e\u9a8c\u8868\u660e\uff0c CTMAB- \u7c98\u571f\u5904\u7406\u6c34\u4e2d\u6709\u673a\u7269\u7684\u6700\u4f73\u9002\u5b9c\u6761\u4ef6\u4e3a\uff1a\u5728 pH \u503c\u4e3a 9 \u65f6\uff0c\u5728\u6bcf \u5347\u6c34\u4e2d\u52a0\u5165 20g\u5438\u9644\u5242\uff0c\u632f\u8361\u65f6\u95f4 60min\uff0c\u5438\u9644\u6548\u7387\u6700\u597d\u3002\u4ed6\u4eec\u8fd8\u53d1\u73b0\uff0c\u540c \u79cd\u6709\u673a\u7c98\u571f\u5904\u7406\u4e0d\u540c\u6709\u673a\u7269\u65f6\uff0c\u5bf9\u785d\u57fa\u82ef\u915a\u7684\u53bb\u9664\u6548\u679c\u6700\u597d\uff1b\u4e0d\u540c\u6709\u673a\u7c98 \u571f\u5904\u7406\u540c\u79cd\u6709\u673a\u7269\u65f6\uff0cCTMAB- \u81a8\u6da6\u571f\u53bb\u9664\u6709\u673a\u7269\u7684\u6548\u679c\u6700\u597d\u3002Wolfe \u7b49 \u7528\u8102\u80aa\u9178\u76d0\u6539\u6027\u8499\u8131\u77f3\u4ee5\u589e\u5f3a\u5438\u9644\u80fd\u529b, \u53d1\u73b0\u7528\u4e0d\u540c\u78b3\u94fe\u5b63\u94f5\u76d0\u6539\u6027\u7684 \u81a8\u6da6\u571f,\u5176\u5c42\u95f4\u8ddd\u3001\u5b54\u5bb9\u53ca\u5185\u8868\u9762\u8f83\u539f\u571f\u90fd\u5927\u5927\u589e\u52a0\uff0c\u7531\u6b64\u6539\u5584\u4e86\u81a8\u6da6\u571f \u5438\u9644\u6c34\u4e2d\u6709\u673a\u7269\u7684\u80fd\u529b\u3002<\/p>\n

5 \u7ed3\u8bba<\/strong><\/p>\n

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